Chemistry Impact Question Title * 1. The survey that you are about to take is part of an effort to understand how chemists place importance on published research. The researchers hope to observe some generalizable trends with respect to how respondents answer these questions. This survey is meant to reach trained chemists: graduate students, postdocs, faculty members, chemical professionals, and trained chemists currently working in a non-research capacity. You will be asked four questions in which you will rank articles from an issue of JACS according to different criteria. You will also be asked to input some very basic demographic information. You are will be provided with an opportunity not to answer the demographic questions. The survey will maintain your anonymity and, in doing so, will minimize any risk that you, the respondent, may incur.If you agree to take part in this survey and have your data analyzed as part of an anonymous data set, please click “yes” to the following question and proceed with the survey. If you do not with to take part in this survey, please exit from this browser window.Do you agree that your submitted answers may be used by the researchers as described above? Yes No Question Title * 2. What is your current occupation? Graduate Student Postdoc Faculty Member Professional within a chemical industry Trained chemist in a non-research field I decline to answer this question Question Title * 3. What is your age? 20-30 30-40 40-50 50-60 60-70 Above 70 I decline to answer this question Question Title * 4. What subdiscipline of chemistry would you say your training is most closely associated with? Analytical Biochemistry Inorganic Organic Medicinal Physical Polymers Other I decline to answer this question Question Title * 5. This question asks you to very briefly evaluate articles in issue 31 of the Journal of the American Chemical Society from 2003. Please click on the link to see authors, abstracts, and article content if this information would be important to the way you answer this question. Which three papers in the issue do YOU think are the most 'significant' (your own definition of 'significant' is what is important here)? Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate Chain Elongations by Three Carbon Atoms at a Time in the Boron-Catalyzed Polymerization of Methallyltriphenylarsonium Ylide The First Triple Thiol-thiolate Hydrogen Bond versus Triple Diselenide Bond That Bridges Two Metal Centers Bulky Aluminum Alkyl Scavengers in Olefin Polymerization with Group 4 Catalysts An Ionic Liquid-Supported Ruthenium Carbene Complex: A Robust and Recyclable Catalyst for Ring-Closing Olefin Metathesis in Ionic Liquids Tin-Centered Radical and Cation: Stable and Free Purely Site-Specific Chemisorption and Conformation of Trimethylamine on Si(100)c(4 × 2) First Examples of Organophosphorus-Containing Materials for Light-Emitting Diodes Solventless Polymerization: Spatial Migration of a Catalyst To Form Polymeric Thin Films in Microchannels Single-Step in Situ Synthesis of Polymer-Grafted Single-Wall Nanotube Composites A Cationic Guest in a 24+ Cationic Host Stereoelectronic Effects on Collagen Stability: The Dichotomy of 4-Fluoroproline Diastereomers Molybdenum−Phosphorus Triple Bond Stabilization by Ancillary Alkoxide Ligation: Synthesis and Structure of a Terminal Phosphide Tris-1-methylcyclohexanoxide Complex Synthesis, Structure, and Photoelectronic Effects of a Uranium−Zinc−Organic Coordination Polymer Containing Infinite Metal Oxide Sheets [3+3]Cycloalkyne Dimers Linked by an Azo Group: A Stable cis-Azo Compound Forms Polymeric Aggregates by Nonplanar π−π Interactions Activation of Alkyl Halides via a Silver-Catalyzed Carbene Insertion Process A Cryptand/Bisparaquat [3]Pseudorotaxane by Cooperative Complexation TNA Synthesis by DNA Polymerases Unusual Effects in the Pd-Catalyzed Asymmetric Allylic Alkylations: Synthesis of Chiral Chromans Stereospecific Photochemical Ring Expansion of Lithiated Benzamides Effect of Catenation on Protein Folding Stability Palladium-Catalyzed [3+2] Intramolecular Cycloaddition of Alk-5-ynylidenecyclopropanes: A Rapid, Practical Approach to Bicyclo[3.3.0]octenes Cucurbit[6]uril Pseudorotaxanes: Distinctive Gas-Phase Dissociation and Reactivity Φ-Values beyond the Ribosomally Encoded Amino Acids: Kinetic and Thermodynamic Consequences of Incorporating Trifluoromethyl Amino Acids in a Globular Protein Meta-Conjugation and Excited-State Coupling in Phenylacetylene Dendrimers Mutasynthesis of Enterocin and Wailupemycin Analogues Studying the Interaction of α-Gal Carbohydrate Antigen and Proteins by Quartz-Crystal Microbalance A New Ruthenium-Catalyzed Cleavage of a Carbon−Carbon Triple Bond: Efficient Transformation of Ethynyl Alcohol into Alkene and Carbon Monoxide Design of Base-Discriminating Fluorescent Nucleoside and Its Application to T/C SNP Typing Formation of Nanostructured Polymer Filaments in Nanochannels Addition of Stable Nitroxide Radical to Stable Divalent Compounds of Heavier Group 14 Elements Diamond Formation by Reduction of Carbon Dioxide at Low Temperatures Epicocconone, A Novel Fluorescent Compound from the Fungus Epicoccum nigrum A New Class of Modular Chiral Ligands with Fluxional Groups 3-Boronoacrolein as an Exceptional Heterodiene in the Highly Enantio- and Diastereoselective Cr(III)-Catalyzed Three-Component [4+2]/Allylboration A Stable Silicon Congener of Highly Strained Bicyclo[3.2.0]hepta-1,3,6-triene Effect of Surface Pressure on the Insulator to Metal Transition of a Langmuir Polyaniline Monolayer Partitioning the Loss in Vancomycin Binding Affinity for d-Ala-d-Lac into Lost H-Bond and Repulsive Lone Pair Contributions Inactivation of Acetyl-CoA Synthase/Carbon Monoxide Dehydrogenase by Copper A Combined Experimental and Theoretical Study of Divalent Metal Ion Selectivity and Function in Proteins: Application to E. coli Ribonuclease H1 Control of Kinetics and Thermodynamics of [1,5]-Shifts by Aromaticity: A View through the Prism of Marcus Theory Study of the Chemistry of ortho- and para-Biphenylnitrenes by Laser Flash Photolysis and Time-Resolved IR Experiments and by B3LYP and CASPT2 Calculations Factors that Determine the Protein Resistance of Oligoether Self-Assembled Monolayers − Internal Hydrophilicity, Terminal Hydrophilicity, and Lateral Packing Density First Pseudorotaxane-Like [3]Complexes Based on Cryptands and Paraquat: Self-Assembly and Crystal Structures A Heterocyclic Peptide Nanotube Role of Charge-Transfer Configurations on the Addition Reaction of Aminoalkyl Radicals onto Acrylate Double Bonds Resolution of the Non-Steady-State Kinetics of the Two-Step Mechanism for the Diels−Alder Reaction between Anthracene and Tetracyanoethylene in Acetonitrile “Belt and Braces”: A Peptide-Based Linker System of de Novo Design The Role of the HOOO- Anion in the Ozonation of Alcohols: Large Differences in the Gas-Phase and in the Solution-Phase Mechanism Design of Heterogeneous Catalysts via Multiple Active Site Positioning in Organic−Inorganic Hybrid Materials Easily Processable Phenylene−Thiophene-Based Organic Field-Effect Transistors and Solution-Fabricated Nonvolatile Transistor Memory Elements Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines Synthesis, Solid-State Crystal Structure, and Reactivity of a Monomeric Copper(I) Anilido Complex Mechanisms of C−C and C−H Alkane Reductive Eliminations from Octahedral Pt(IV): Reaction via Five-Coordinate Intermediates or Direct Elimination? Quantitative Measure for the “Nakedness” of Fluoride Ion Sources Cationic Hafnium Silyl Complexes and Their Enhanced Reactivity in σ-Bond Metathesis Processes with Si−H and C−H Bonds Cationic Assembly of Metal Complex Aggregates: Structural Diversity, Solution Stability, and Magnetic Properties α- and β-A2Hg3M2S8 (A = K, Rb; M = Ge, Sn): Polar Quaternary Chalcogenides with Strong Nonlinear Optical Response Electronic Excitation Energies of ZniOi Clusters Structure and Phase Transitions of Alkyl Chains on Mica Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC4M‘]n+: Computational Analyses of the Effect of the Metal On the Nonpolar Hydration Free Energy of Proteins: Surface Area and Continuum Solvent Models for the Solute−Solvent Interaction Energy Influence of Delocalization on the Stability of Dianions: Study of a Systematic Series of Dianions with Growing Electronic Localization Question Title * 6. This question asks you to very briefly evaluate articles in issue 31 of the Journal of the American Chemical Society from 2003. Please click on the link to see authors, abstracts, and article content if this information would be important to the way you answer this question. Without looking up the numbers, which three papers do you think will have been cited the most to-date? Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate Chain Elongations by Three Carbon Atoms at a Time in the Boron-Catalyzed Polymerization of Methallyltriphenylarsonium Ylide The First Triple Thiol-thiolate Hydrogen Bond versus Triple Diselenide Bond That Bridges Two Metal Centers Bulky Aluminum Alkyl Scavengers in Olefin Polymerization with Group 4 Catalysts An Ionic Liquid-Supported Ruthenium Carbene Complex: A Robust and Recyclable Catalyst for Ring-Closing Olefin Metathesis in Ionic Liquids Tin-Centered Radical and Cation: Stable and Free Purely Site-Specific Chemisorption and Conformation of Trimethylamine on Si(100)c(4 × 2) First Examples of Organophosphorus-Containing Materials for Light-Emitting Diodes Solventless Polymerization: Spatial Migration of a Catalyst To Form Polymeric Thin Films in Microchannels Single-Step in Situ Synthesis of Polymer-Grafted Single-Wall Nanotube Composites A Cationic Guest in a 24+ Cationic Host Stereoelectronic Effects on Collagen Stability: The Dichotomy of 4-Fluoroproline Diastereomers Molybdenum−Phosphorus Triple Bond Stabilization by Ancillary Alkoxide Ligation: Synthesis and Structure of a Terminal Phosphide Tris-1-methylcyclohexanoxide Complex Synthesis, Structure, and Photoelectronic Effects of a Uranium−Zinc−Organic Coordination Polymer Containing Infinite Metal Oxide Sheets [3+3]Cycloalkyne Dimers Linked by an Azo Group: A Stable cis-Azo Compound Forms Polymeric Aggregates by Nonplanar π−π Interactions Activation of Alkyl Halides via a Silver-Catalyzed Carbene Insertion Process A Cryptand/Bisparaquat [3]Pseudorotaxane by Cooperative Complexation TNA Synthesis by DNA Polymerases Unusual Effects in the Pd-Catalyzed Asymmetric Allylic Alkylations: Synthesis of Chiral Chromans Stereospecific Photochemical Ring Expansion of Lithiated Benzamides Effect of Catenation on Protein Folding Stability Palladium-Catalyzed [3+2] Intramolecular Cycloaddition of Alk-5-ynylidenecyclopropanes: A Rapid, Practical Approach to Bicyclo[3.3.0]octenes Cucurbit[6]uril Pseudorotaxanes: Distinctive Gas-Phase Dissociation and Reactivity Φ-Values beyond the Ribosomally Encoded Amino Acids: Kinetic and Thermodynamic Consequences of Incorporating Trifluoromethyl Amino Acids in a Globular Protein Meta-Conjugation and Excited-State Coupling in Phenylacetylene Dendrimers Mutasynthesis of Enterocin and Wailupemycin Analogues Studying the Interaction of α-Gal Carbohydrate Antigen and Proteins by Quartz-Crystal Microbalance A New Ruthenium-Catalyzed Cleavage of a Carbon−Carbon Triple Bond: Efficient Transformation of Ethynyl Alcohol into Alkene and Carbon Monoxide Design of Base-Discriminating Fluorescent Nucleoside and Its Application to T/C SNP Typing Formation of Nanostructured Polymer Filaments in Nanochannels Addition of Stable Nitroxide Radical to Stable Divalent Compounds of Heavier Group 14 Elements Diamond Formation by Reduction of Carbon Dioxide at Low Temperatures Epicocconone, A Novel Fluorescent Compound from the Fungus Epicoccum nigrum A New Class of Modular Chiral Ligands with Fluxional Groups 3-Boronoacrolein as an Exceptional Heterodiene in the Highly Enantio- and Diastereoselective Cr(III)-Catalyzed Three-Component [4+2]/Allylboration A Stable Silicon Congener of Highly Strained Bicyclo[3.2.0]hepta-1,3,6-triene Effect of Surface Pressure on the Insulator to Metal Transition of a Langmuir Polyaniline Monolayer Partitioning the Loss in Vancomycin Binding Affinity for d-Ala-d-Lac into Lost H-Bond and Repulsive Lone Pair Contributions Inactivation of Acetyl-CoA Synthase/Carbon Monoxide Dehydrogenase by Copper A Combined Experimental and Theoretical Study of Divalent Metal Ion Selectivity and Function in Proteins: Application to E. coli Ribonuclease H1 Control of Kinetics and Thermodynamics of [1,5]-Shifts by Aromaticity: A View through the Prism of Marcus Theory Study of the Chemistry of ortho- and para-Biphenylnitrenes by Laser Flash Photolysis and Time-Resolved IR Experiments and by B3LYP and CASPT2 Calculations Factors that Determine the Protein Resistance of Oligoether Self-Assembled Monolayers − Internal Hydrophilicity, Terminal Hydrophilicity, and Lateral Packing Density First Pseudorotaxane-Like [3]Complexes Based on Cryptands and Paraquat: Self-Assembly and Crystal Structures A Heterocyclic Peptide Nanotube Role of Charge-Transfer Configurations on the Addition Reaction of Aminoalkyl Radicals onto Acrylate Double Bonds Resolution of the Non-Steady-State Kinetics of the Two-Step Mechanism for the Diels−Alder Reaction between Anthracene and Tetracyanoethylene in Acetonitrile “Belt and Braces”: A Peptide-Based Linker System of de Novo Design The Role of the HOOO- Anion in the Ozonation of Alcohols: Large Differences in the Gas-Phase and in the Solution-Phase Mechanism Design of Heterogeneous Catalysts via Multiple Active Site Positioning in Organic−Inorganic Hybrid Materials Easily Processable Phenylene−Thiophene-Based Organic Field-Effect Transistors and Solution-Fabricated Nonvolatile Transistor Memory Elements Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines Synthesis, Solid-State Crystal Structure, and Reactivity of a Monomeric Copper(I) Anilido Complex Mechanisms of C−C and C−H Alkane Reductive Eliminations from Octahedral Pt(IV): Reaction via Five-Coordinate Intermediates or Direct Elimination? Quantitative Measure for the “Nakedness” of Fluoride Ion Sources Cationic Hafnium Silyl Complexes and Their Enhanced Reactivity in σ-Bond Metathesis Processes with Si−H and C−H Bonds Cationic Assembly of Metal Complex Aggregates: Structural Diversity, Solution Stability, and Magnetic Properties α- and β-A2Hg3M2S8 (A = K, Rb; M = Ge, Sn): Polar Quaternary Chalcogenides with Strong Nonlinear Optical Response Electronic Excitation Energies of ZniOi Clusters Structure and Phase Transitions of Alkyl Chains on Mica Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC4M‘]n+: Computational Analyses of the Effect of the Metal On the Nonpolar Hydration Free Energy of Proteins: Surface Area and Continuum Solvent Models for the Solute−Solvent Interaction Energy Influence of Delocalization on the Stability of Dianions: Study of a Systematic Series of Dianions with Growing Electronic Localization Question Title * 7. This question asks you to very briefly evaluate articles in issue 31 of the Journal of the American Chemical Society from 2003. Please click on the link to see authors, abstracts, and article content if this information would be important to the way you answer this question. Which three papers would you most want to point out to other chemists? Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate Chain Elongations by Three Carbon Atoms at a Time in the Boron-Catalyzed Polymerization of Methallyltriphenylarsonium Ylide The First Triple Thiol-thiolate Hydrogen Bond versus Triple Diselenide Bond That Bridges Two Metal Centers Bulky Aluminum Alkyl Scavengers in Olefin Polymerization with Group 4 Catalysts An Ionic Liquid-Supported Ruthenium Carbene Complex: A Robust and Recyclable Catalyst for Ring-Closing Olefin Metathesis in Ionic Liquids Tin-Centered Radical and Cation: Stable and Free Purely Site-Specific Chemisorption and Conformation of Trimethylamine on Si(100)c(4 × 2) First Examples of Organophosphorus-Containing Materials for Light-Emitting Diodes Solventless Polymerization: Spatial Migration of a Catalyst To Form Polymeric Thin Films in Microchannels Single-Step in Situ Synthesis of Polymer-Grafted Single-Wall Nanotube Composites A Cationic Guest in a 24+ Cationic Host Stereoelectronic Effects on Collagen Stability: The Dichotomy of 4-Fluoroproline Diastereomers Molybdenum−Phosphorus Triple Bond Stabilization by Ancillary Alkoxide Ligation: Synthesis and Structure of a Terminal Phosphide Tris-1-methylcyclohexanoxide Complex Synthesis, Structure, and Photoelectronic Effects of a Uranium−Zinc−Organic Coordination Polymer Containing Infinite Metal Oxide Sheets [3+3]Cycloalkyne Dimers Linked by an Azo Group: A Stable cis-Azo Compound Forms Polymeric Aggregates by Nonplanar π−π Interactions Activation of Alkyl Halides via a Silver-Catalyzed Carbene Insertion Process A Cryptand/Bisparaquat [3]Pseudorotaxane by Cooperative Complexation TNA Synthesis by DNA Polymerases Unusual Effects in the Pd-Catalyzed Asymmetric Allylic Alkylations: Synthesis of Chiral Chromans Stereospecific Photochemical Ring Expansion of Lithiated Benzamides Effect of Catenation on Protein Folding Stability Palladium-Catalyzed [3+2] Intramolecular Cycloaddition of Alk-5-ynylidenecyclopropanes: A Rapid, Practical Approach to Bicyclo[3.3.0]octenes Cucurbit[6]uril Pseudorotaxanes: Distinctive Gas-Phase Dissociation and Reactivity Φ-Values beyond the Ribosomally Encoded Amino Acids: Kinetic and Thermodynamic Consequences of Incorporating Trifluoromethyl Amino Acids in a Globular Protein Meta-Conjugation and Excited-State Coupling in Phenylacetylene Dendrimers Mutasynthesis of Enterocin and Wailupemycin Analogues Studying the Interaction of α-Gal Carbohydrate Antigen and Proteins by Quartz-Crystal Microbalance A New Ruthenium-Catalyzed Cleavage of a Carbon−Carbon Triple Bond: Efficient Transformation of Ethynyl Alcohol into Alkene and Carbon Monoxide Design of Base-Discriminating Fluorescent Nucleoside and Its Application to T/C SNP Typing Formation of Nanostructured Polymer Filaments in Nanochannels Addition of Stable Nitroxide Radical to Stable Divalent Compounds of Heavier Group 14 Elements Diamond Formation by Reduction of Carbon Dioxide at Low Temperatures Epicocconone, A Novel Fluorescent Compound from the Fungus Epicoccum nigrum A New Class of Modular Chiral Ligands with Fluxional Groups 3-Boronoacrolein as an Exceptional Heterodiene in the Highly Enantio- and Diastereoselective Cr(III)-Catalyzed Three-Component [4+2]/Allylboration A Stable Silicon Congener of Highly Strained Bicyclo[3.2.0]hepta-1,3,6-triene Effect of Surface Pressure on the Insulator to Metal Transition of a Langmuir Polyaniline Monolayer Partitioning the Loss in Vancomycin Binding Affinity for d-Ala-d-Lac into Lost H-Bond and Repulsive Lone Pair Contributions Inactivation of Acetyl-CoA Synthase/Carbon Monoxide Dehydrogenase by Copper A Combined Experimental and Theoretical Study of Divalent Metal Ion Selectivity and Function in Proteins: Application to E. coli Ribonuclease H1 Control of Kinetics and Thermodynamics of [1,5]-Shifts by Aromaticity: A View through the Prism of Marcus Theory Study of the Chemistry of ortho- and para-Biphenylnitrenes by Laser Flash Photolysis and Time-Resolved IR Experiments and by B3LYP and CASPT2 Calculations Factors that Determine the Protein Resistance of Oligoether Self-Assembled Monolayers − Internal Hydrophilicity, Terminal Hydrophilicity, and Lateral Packing Density First Pseudorotaxane-Like [3]Complexes Based on Cryptands and Paraquat: Self-Assembly and Crystal Structures A Heterocyclic Peptide Nanotube Role of Charge-Transfer Configurations on the Addition Reaction of Aminoalkyl Radicals onto Acrylate Double Bonds Resolution of the Non-Steady-State Kinetics of the Two-Step Mechanism for the Diels−Alder Reaction between Anthracene and Tetracyanoethylene in Acetonitrile “Belt and Braces”: A Peptide-Based Linker System of de Novo Design The Role of the HOOO- Anion in the Ozonation of Alcohols: Large Differences in the Gas-Phase and in the Solution-Phase Mechanism Design of Heterogeneous Catalysts via Multiple Active Site Positioning in Organic−Inorganic Hybrid Materials Easily Processable Phenylene−Thiophene-Based Organic Field-Effect Transistors and Solution-Fabricated Nonvolatile Transistor Memory Elements Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines Synthesis, Solid-State Crystal Structure, and Reactivity of a Monomeric Copper(I) Anilido Complex Mechanisms of C−C and C−H Alkane Reductive Eliminations from Octahedral Pt(IV): Reaction via Five-Coordinate Intermediates or Direct Elimination? Quantitative Measure for the “Nakedness” of Fluoride Ion Sources Cationic Hafnium Silyl Complexes and Their Enhanced Reactivity in σ-Bond Metathesis Processes with Si−H and C−H Bonds Cationic Assembly of Metal Complex Aggregates: Structural Diversity, Solution Stability, and Magnetic Properties α- and β-A2Hg3M2S8 (A = K, Rb; M = Ge, Sn): Polar Quaternary Chalcogenides with Strong Nonlinear Optical Response Electronic Excitation Energies of ZniOi Clusters Structure and Phase Transitions of Alkyl Chains on Mica Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC4M‘]n+: Computational Analyses of the Effect of the Metal On the Nonpolar Hydration Free Energy of Proteins: Surface Area and Continuum Solvent Models for the Solute−Solvent Interaction Energy Influence of Delocalization on the Stability of Dianions: Study of a Systematic Series of Dianions with Growing Electronic Localization Question Title * 8. This question asks you to very briefly evaluate articles in issue 31 of the Journal of the American Chemical Society from 2003. Please click on the link to see authors, abstracts, and article content if this information would be important to the way you answer this question. Which three papers would you want to shout about from the rooftops (i.e., tell anybody about, not just chemists)? Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate Chain Elongations by Three Carbon Atoms at a Time in the Boron-Catalyzed Polymerization of Methallyltriphenylarsonium Ylide The First Triple Thiol-thiolate Hydrogen Bond versus Triple Diselenide Bond That Bridges Two Metal Centers Bulky Aluminum Alkyl Scavengers in Olefin Polymerization with Group 4 Catalysts An Ionic Liquid-Supported Ruthenium Carbene Complex: A Robust and Recyclable Catalyst for Ring-Closing Olefin Metathesis in Ionic Liquids Tin-Centered Radical and Cation: Stable and Free Purely Site-Specific Chemisorption and Conformation of Trimethylamine on Si(100)c(4 × 2) First Examples of Organophosphorus-Containing Materials for Light-Emitting Diodes Solventless Polymerization: Spatial Migration of a Catalyst To Form Polymeric Thin Films in Microchannels Single-Step in Situ Synthesis of Polymer-Grafted Single-Wall Nanotube Composites A Cationic Guest in a 24+ Cationic Host Stereoelectronic Effects on Collagen Stability: The Dichotomy of 4-Fluoroproline Diastereomers Molybdenum−Phosphorus Triple Bond Stabilization by Ancillary Alkoxide Ligation: Synthesis and Structure of a Terminal Phosphide Tris-1-methylcyclohexanoxide Complex Synthesis, Structure, and Photoelectronic Effects of a Uranium−Zinc−Organic Coordination Polymer Containing Infinite Metal Oxide Sheets [3+3]Cycloalkyne Dimers Linked by an Azo Group: A Stable cis-Azo Compound Forms Polymeric Aggregates by Nonplanar π−π Interactions Activation of Alkyl Halides via a Silver-Catalyzed Carbene Insertion Process A Cryptand/Bisparaquat [3]Pseudorotaxane by Cooperative Complexation TNA Synthesis by DNA Polymerases Unusual Effects in the Pd-Catalyzed Asymmetric Allylic Alkylations: Synthesis of Chiral Chromans Stereospecific Photochemical Ring Expansion of Lithiated Benzamides Effect of Catenation on Protein Folding Stability Palladium-Catalyzed [3+2] Intramolecular Cycloaddition of Alk-5-ynylidenecyclopropanes: A Rapid, Practical Approach to Bicyclo[3.3.0]octenes Cucurbit[6]uril Pseudorotaxanes: Distinctive Gas-Phase Dissociation and Reactivity Φ-Values beyond the Ribosomally Encoded Amino Acids: Kinetic and Thermodynamic Consequences of Incorporating Trifluoromethyl Amino Acids in a Globular Protein Meta-Conjugation and Excited-State Coupling in Phenylacetylene Dendrimers Mutasynthesis of Enterocin and Wailupemycin Analogues Studying the Interaction of α-Gal Carbohydrate Antigen and Proteins by Quartz-Crystal Microbalance A New Ruthenium-Catalyzed Cleavage of a Carbon−Carbon Triple Bond: Efficient Transformation of Ethynyl Alcohol into Alkene and Carbon Monoxide Design of Base-Discriminating Fluorescent Nucleoside and Its Application to T/C SNP Typing Formation of Nanostructured Polymer Filaments in Nanochannels Addition of Stable Nitroxide Radical to Stable Divalent Compounds of Heavier Group 14 Elements Diamond Formation by Reduction of Carbon Dioxide at Low Temperatures Epicocconone, A Novel Fluorescent Compound from the Fungus Epicoccum nigrum A New Class of Modular Chiral Ligands with Fluxional Groups 3-Boronoacrolein as an Exceptional Heterodiene in the Highly Enantio- and Diastereoselective Cr(III)-Catalyzed Three-Component [4+2]/Allylboration A Stable Silicon Congener of Highly Strained Bicyclo[3.2.0]hepta-1,3,6-triene Effect of Surface Pressure on the Insulator to Metal Transition of a Langmuir Polyaniline Monolayer Partitioning the Loss in Vancomycin Binding Affinity for d-Ala-d-Lac into Lost H-Bond and Repulsive Lone Pair Contributions Inactivation of Acetyl-CoA Synthase/Carbon Monoxide Dehydrogenase by Copper A Combined Experimental and Theoretical Study of Divalent Metal Ion Selectivity and Function in Proteins: Application to E. coli Ribonuclease H1 Control of Kinetics and Thermodynamics of [1,5]-Shifts by Aromaticity: A View through the Prism of Marcus Theory Study of the Chemistry of ortho- and para-Biphenylnitrenes by Laser Flash Photolysis and Time-Resolved IR Experiments and by B3LYP and CASPT2 Calculations Factors that Determine the Protein Resistance of Oligoether Self-Assembled Monolayers − Internal Hydrophilicity, Terminal Hydrophilicity, and Lateral Packing Density First Pseudorotaxane-Like [3]Complexes Based on Cryptands and Paraquat: Self-Assembly and Crystal Structures A Heterocyclic Peptide Nanotube Role of Charge-Transfer Configurations on the Addition Reaction of Aminoalkyl Radicals onto Acrylate Double Bonds Resolution of the Non-Steady-State Kinetics of the Two-Step Mechanism for the Diels−Alder Reaction between Anthracene and Tetracyanoethylene in Acetonitrile “Belt and Braces”: A Peptide-Based Linker System of de Novo Design The Role of the HOOO- Anion in the Ozonation of Alcohols: Large Differences in the Gas-Phase and in the Solution-Phase Mechanism Design of Heterogeneous Catalysts via Multiple Active Site Positioning in Organic−Inorganic Hybrid Materials Easily Processable Phenylene−Thiophene-Based Organic Field-Effect Transistors and Solution-Fabricated Nonvolatile Transistor Memory Elements Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines Synthesis, Solid-State Crystal Structure, and Reactivity of a Monomeric Copper(I) Anilido Complex Mechanisms of C−C and C−H Alkane Reductive Eliminations from Octahedral Pt(IV): Reaction via Five-Coordinate Intermediates or Direct Elimination? Quantitative Measure for the “Nakedness” of Fluoride Ion Sources Cationic Hafnium Silyl Complexes and Their Enhanced Reactivity in σ-Bond Metathesis Processes with Si−H and C−H Bonds Cationic Assembly of Metal Complex Aggregates: Structural Diversity, Solution Stability, and Magnetic Properties α- and β-A2Hg3M2S8 (A = K, Rb; M = Ge, Sn): Polar Quaternary Chalcogenides with Strong Nonlinear Optical Response Electronic Excitation Energies of ZniOi Clusters Structure and Phase Transitions of Alkyl Chains on Mica Bonding and Electronic Structure in Consanguineous and Conjugal Iron and Rhenium sp Carbon Chain Complexes [MC4M‘]n+: Computational Analyses of the Effect of the Metal On the Nonpolar Hydration Free Energy of Proteins: Surface Area and Continuum Solvent Models for the Solute−Solvent Interaction Energy Influence of Delocalization on the Stability of Dianions: Study of a Systematic Series of Dianions with Growing Electronic Localization Done